Is this a good battery for my portable Wii?

Yes, this will certainly work. The wiis regulators can handle it. However, I would recommend going to batteryspace.com and getting a better, less expensive pack.
How long it will last is a very broad question.
If you use a 90nm wii board, I would guess 2.5 hours, and if you used a 65nm wii board I would guess 4-5 hours.
 
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