Copper has almost twice the thermal conductivity than aluminum, but that does not mean it's better. Aluminum weighs 3 times less than copper, and on a handheld, weight matters. If N64s required excessive heatsinking, copper would be better, but since the N64 doesn't get very hot, an aluminum heatsink works nearly as well as a copper one, and is way lighter. For a weight to thermal conductivity ratio, Aluminum is better than copper.
That being said, those heatsinks bassmata linked are great and perfect size, but you have to buy 2 packs.